A Dynamic Model to Simulate Arsenic,Lead, and Mercury Contamination in the Terrestrial Environment During Extreme Floods of Rivers     

Marcus Schulz  Olaf Büttner  Martina Baborowski  Michael Böhme  Michael Matthies  Wolf von Tümpling 《洁净——土壤、空气、水》2009,37(3):209-217

Beside damages of infrastructure in industrial regions, extreme floods can cause contamination with particle‐bound pollutants, e. g., due to erosion of soils and sediments. In order to predict contamination with inorganic pollutants, the transport and fate of arsenic, lead, and mercury during a fictive flood event of River Vereinigte Mulde in the region of Bitterfeld (Germany) with 200 years recurrence time was modeled. The finite element model system Telemac2D, which is subdivided into a hydrodynamic (Telemac‐2D), a transport (Subief‐2D), and a water quality module (wq2subief) was applied. The transport and water quality model models were calibrated using results of sediment trap exposures in the floodplain of River Vereinigte Mulde. Model results exhibited that the spatial patterns of particle‐associated arsenic and lead concentrations significantly changed. Extended, mostly agriculturally used areas showed arsenic and lead concentrations between 150 and 200 mg kg^–1 and 250 and 300 mg kg^–1, respectively, while urban areas were to a great extent spared from high contamination with arsenic and lead. Concentrations of particle‐associated mercury showed a pattern distinct from those of arsenic and lead. Outside of small patches with concentrations up to 63 mg kg^–1, concentrations of particle‐associated mercury remained close to zero. Differences in the spatial patterns of the three pollutants regarded mainly arise from significantly different initial and boundary conditions. Sensitivity analyses of initial and boundary conditions revealed a high sensitivity of particle‐bound pollutant concentrations, whereas the sensitivities of concentrations of suspended sediments and soluble pollutants were mediocre to negligible.  相似文献   

Selective zooplanktivory of an invasive Ponto-Caspian mysid and possible consequences for the zooplankton community structure of invaded habitats     

Patrick?FinkEmail author  Anke?Kottsieper  Martina?Heynen  Jost?Borcherding 《Aquatic Sciences - Research Across Boundaries》2012,74(1):191-202

The impact of invasive alien species on native species is of increasing global concern. Invasive species can cause food-web shifts that have severe consequences for native species and ecosystems. However, the mechanisms by which the invaders influence the native communities are poorly understood. Here we investigated the interactions of the invasive Ponto-Caspian mysid Limnomysis benedeni with native freshwater zooplankton in laboratory and mesocosm experiments. This mysid migrates between benthic and pelagic zones and thereby forms a potential trophic link between these habitats. In laboratory predation experiments, L. benedeni fed both on Daphnia galeata and D. magna, and predation rates depended on the sizes of predator and prey but not on the availability of light. However, no predation was observed at prey sizes greater than 2 mm, which appears to be the upper size limit for a successful prey capture by L. benedeni. In outdoor mesocosm experiments, L. benedeni strongly decreased the densities of cladocerans, rotifers and copepod nauplii within a few days, while the densities of copepods were unaffected. Prey selection indices provide further evidence for strongly selective predation of L. benedeni on different zooplankton taxa. The presence of phytoplankton as an additional resource for the omnivorous mysid led to a lower predation pressure of L. benedeni on Cladocera and rotifers, indicating that the presence of alternative prey modulates the strength of the top-down effect of invasive mysids on the zooplankton community. These results suggest that the invasion of L. benedeni can have profound and complex impacts on the community structure of the native zooplankton fauna and that mysid invasions potentially have whole-ecosystem consequences.  相似文献   

Global Xenon-133 Emission Inventory Caused by Medical Isotope Production and Derived from the Worldwide Technetium-99m Demand     

Martin B. Kalinowski  Martina Grosch  Simon Hebel 《Pure and Applied Geophysics》2014,171(3-5):707-716

Emissions from medical isotope production are the most important source of background for atmospheric radioxenon measurements, which are an essential part of nuclear explosion monitoring. This article presents a new approach for estimating the global annual radioxenon emission inventory caused by medical isotope production using the amount of Tc-99m applications in hospitals as the basis. Tc-99m is the most commonly used isotope in radiology and dominates the medical isotope production. This paper presents the first estimate of the global production of Tc-99m. Depending on the production and transport scenario, global xenon emissions of 11–45 PBq/year can be derived from the global isotope demand. The lower end of this estimate is in good agreement with other estimations which are making use of reported releases and realistic process simulations. This proves the validity of the complementary assessment method proposed in this paper. It may be of relevance for future emission scenarios and for estimating the contribution to the global source term from countries and operators that do not make sufficient radioxenon release information available. It depends on sound data on medical treatments with radio-pharmaceuticals and on technical information on the production process of the supplier. This might help in understanding the apparent underestimation of the global emission inventory that has been found by atmospheric transport modelling.  相似文献   

Geochemical and organic petrological characterization of the organic matter of lacustrine Eocene oil shales (Prinz von Hessen,Germany): reconstruction of the depositional environment     

Peter?HofmannEmail author  Martina?Duckensell  Arkadi?Chpitsglous  Lorenz?Schwark 《Journal of Paleolimnology》2005,33(2):155-168

Optical and geochemical techniques were applied to sedimentary organic matter from the profundal area of the Eocene Lake Prinz von Hessen, which formed in a pull-apart basin on the Sprendlinger Horst, near Darmstadt, Germany. Variations in total sulphur content (S tot) and total organic carbon content (TOC), hydrogen index (HI), oxygen index (OI) and ¹³C values of the organic matter were used to reconstruct the lakes filling history. Following an initial rapid deepening phase, open lake conditions developed with HI reaching more than 500 mg HC/g TOC and TOC values up to 40%. The productivity of the lake was probably high and organic matter preservation was enhanced by a stratified water column. As the lake began to fill with sediment and became shallower, TOC and HI values declined, as the lake water was better oxygenated and preservation conditions declined. ¹³C values between –31 and –27 are controlled by the mixing of aquatic (algae and microbial mats) and terrigenous organic matter (wood, spores, pollen and cuticles). Following a rapid drop in lake level, shallow lake conditions alternated with swamp deposits (lignites) in the basin center. The organic matter preserved during this stage is strictly terrigenous in nature and experienced oxic degradation (HI 100 mg HC/g TOC). ¹³C values between –26 and –24 are typical for Eocene terrigenous matter. The inferred lake level fluctuations are interpreted to have been controlled by tectonic as well as climatic processes.  相似文献   

Characterization of elemental release during microbe-basalt interactions at T = 28 °C     

Lingling Wu  Andrew D. Jacobson  Martina Hausner 《Geochimica et cosmochimica acta》2007,71(9):2224-2239

This study used batch reactors to characterize the rates and mechanisms of elemental release during the interaction of a single bacterial species (Burkholderia fungorum) with Columbia River Flood Basalt at T = 28 °C for 36 days. We primarily examined the release of Ca, Mg, P, Si, and Sr under a variety of biotic and abiotic conditions with the aim of evaluating how actively metabolizing bacteria might influence basalt weathering on the continents. Four days after inoculating P-limited reactors (those lacking P in the growth medium), the concentration of viable planktonic cells increased from ∼10⁴ to 10⁸ CFU (Colony Forming Units)/mL, pH decreased from ∼7 to 4, and glucose decreased from ∼1200 to 0 μmol/L. Mass-balance and acid-base equilibria calculations suggest that the lowered pH resulted from either respired CO₂, organic acids released during biomass synthesis, or H⁺ extrusion during uptake. Between days 4 and 36, cell numbers remained constant at ∼10⁸ CFU/mL and pH increased to ∼5. Purely abiotic control reactors as well as control reactors containing inert cells (∼10⁸ CFU/mL) showed constant glucose concentrations, thus confirming the absence of biological activity in these experiments. The pH of all control reactors remained near-neutral, except for one experiment where the pH was initially adjusted to 4 but rapidly rose to 7 within 2 days. Over the entire 36 day period, P-limited reactors containing viable bacteria yielded the highest Ca, Mg, Si, and Sr release rates. Release rates inversely correlate with pH, indicating that proton-promoted dissolution was the dominant reaction mechanism. Both biotic and abiotic P-limited reactors displayed low P concentrations. Chemical analyses of bacteria collected at the end of the experiments, combined with mass-balances between the biological and fluid phases, demonstrate that the absence of dissolved P in the biotic reactors resulted from microbial P uptake. The only P source in the basalt is a small amount of apatite (∼1.2%), which occurs as needles within feldspar grains and glass. We therefore conclude that B. fungorum utilized apatite as a P source for biomass synthesis, which stimulated elemental release from coexisting mineral phases via pH lowering. The results of this study suggest that actively metabolizing bacteria have the potential to influence elemental release from basalt in continental settings.  相似文献   

Al Huwaysah 010: The most reduced brachinite,so far     

Cristian Carli  Anna Barbaro  Mara Murri  Maria Chiara Domeneghetti  Antonio Langone  Enrico Bruschini  Alice Stephant  Matteo Alvaro  Stefania Stefani  Tiberio Cuppone  Martina Casalini  Alessandra Migliorini  Ted L. Roush  Giovanni Pratesi 《Meteoritics & planetary science》2023,58(6):855-874

Al Huwaysah 010 is an ungrouped achondrite meteorite, recently referred to as a brachinite-like meteorite. This meteorite, showing a fine-grained assemblage of low-Ca pyroxene and opaque phases, is strongly reduced in comparison to other reduced brachinites. The occurrence of some tiny plates of graphite and oldhamite in this meteorite suggests that a partial melt residue has experienced a further reduction process. Olivine, the most abundant phase, is compositionally homogeneous (Fo_83.3) as well as the clinopyroxene (En_45.5Fs_10.8Wo_43.7) and the plagioclase (Ab_69.5). Orthopyroxene (En_85.4Fs_13.9Wo_0.7) also occurs but only in a fine intergrowth. Other accessory phases are Fe metal grains (Ni-free or Cr-bearing Fe-Ni alloy), troilite, chlorapatite, pentlandite (as inclusions in chromite). The sample shows two different closure temperatures: the highest (≈900°C) is determined via the olivine–chromite intercrystalline geothermometer and the lowest temperature (≈520°C) is determined via the pyroxene-based intracrystalline geothermometer. These temperatures may represent, respectively, the closure temperature associated with the formation and a subsequent impact event excavating the sample from the parental body. The visible to near-infrared (VNIR) reflectance spectra of Al Huwaysah 010 exhibit low reflectance, consistent with the presence of darkening components, and weak absorptions indicative of olivine and pyroxene. Comparing the spectral parameters of Al Huwaysah 010 to potential parent bodies characterized by olivine–pyroxene mineralogy, we find that it falls within the field previously attributed to the SIII type asteroids. These results lead us to classify the Al Huwaysah 010 meteorite as the most reduced brachinite, whose VNIR spectral features show strong affinities with those of SIII asteroids.  相似文献   

Dynamical downscaling of CMIP5 global circulation models over CORDEX-Africa with COSMO-CLM: evaluation over the present climate and analysis of the added value   总被引：2，自引：1，他引：1  

Alessandro Dosio  Hans-Jürgen Panitz  Martina Schubert-Frisius  Daniel Lüthi 《Climate Dynamics》2015,44(9-10):2637-2661

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CO<Subscript>2</Subscript> fluid inclusions in Jack Hills zircons     

Martina?MennekenEmail authorView author&#;s OrcID profile  Thorsten?Geisler  Alexander?A.?Nemchin  Martin?J.?Whitehouse  Simon?A.?Wilde  Biliana?Gasharova  Robert?T.?Pidgeon 《Contributions to Mineralogy and Petrology》2017,172(8):66

The discovery of Hadean to Paleoarchean zircons in a metaconglomerate from Jack Hills, Western Australia, has catalyzed intensive study of these zircons and their mineral inclusions, as they represent unique geochemical archives that can be used to unravel the geological evolution of early Earth. Here, we report the occurrence and physical properties of previously undetected CO₂ inclusions that were identified in 3.36–3.47 Ga and 3.80–4.13 Ga zircon grains by confocal micro-Raman spectroscopy. Minimum P–T conditions of zircon formation were determined from the highest density of the inclusions, determined from the density-dependence of the Fermi diad splitting in the Raman spectrum and Ti-in-zircon thermometry. For both age periods, the CO₂ densities and Ti-in-zircon temperatures correspond to high-grade metamorphic conditions (≥5 to ≥7 kbar/~670 to 770 °C) that are typical of mid-crustal regional metamorphism throughout Earth’s history. In addition, fully enclosed, highly disordered graphitic carbon inclusions were identified in two zircon grains from the older population that also contained CO₂ inclusions. Transmission electron microscopy on one of these inclusions revealed that carbon forms a thin amorphous film on the inclusion wall, whereas the rest of the volume was probably occupied by CO₂ prior to analysis. This indicates a close relationship between CO₂ and the reduced carbon inclusions and, in particular that the carbon precipitated from a CO₂-rich fluid, which is inconsistent with the recently proposed biogenic origin of carbon inclusions found in Hadean zircons from Jack Hills.  相似文献   

Assessment of runoff,water and sediment quality in the Selenga River basin aided by a web-based geoservice     

Daniel Karthe  Sergey Chalov  Vsevolod Moreido  Margarita Pashkina  Anna Romanchenko  Gunsmaa Batbayar  Andrei Kalugin  Katja Westphal  Marcus Malsy  Martina Flörke 《Water Resources》2017,44(3):399-416

The Selenga River is the main artery feeding Lake Baikal. It has a catchment of ~450000 km² in the boundary region between Northern Mongolia and Southern Siberia. Climate, land use and dynamic socioeconomic changes go along with rising water abstractions and contaminant loads originating from mining sites and urban wastewater. In the future, these pressures might have negative impacts on the ecosystems of Lake Baikal and the Selenga River Delta, which is an important wetland region in itself and forms the last geobiochemical barrier before the Selenga drains into Lake Baikal. The following study aims to assess current trends in hydrology and water quality in the Selenga-Baikal basin, identify their drivers and to set up models (WaterGAP3 framework and ECOMAG) for the prediction of future changes. Of particular relevance for hydrological and water quality changes in the recent past were climate and land use trends as well as contaminant influx from mining areas and urban settlements. In the near future, additional hydrological modifications due to the construction of dams and abstractions/water diversions from the Selenga’s Mongolian tributaries could lead to additional alterations.  相似文献   

San Quirce (Palencia,Spain): new chronologies for the Lower to Middle Palaeolithic transition of south-west Europe     

Marcos Terradillos-Bernal  Martina Demuro  Lee J. Arnold  Jesús F. Jordá-Pardo  Ignacio Clemente-Conte  Alfonso Benito-Calvo  J. Carlos Díez Fernández-Lomana 《第四纪科学杂志》2023,38(1):21-37

San Quirce is an open-air archaeological site situated on a fluvial terrace in the Duero basin (Palencia, northern Iberia). This paper presents new and consistent chronologies obtained for the sedimentary sequence using post-infrared infrared stimulated luminescence (pIR-IR) dating of K-feldspars and single-grain thermally transferred optically stimulated luminescence (TT-OSL) dating of quartz. The new dating results indicate that the sequence is older than ~200 000 years and place San Quirce Level III within marine isotope stages (MIS) 8 and 7, between 274 ± 13 ka and 238 ± 13 ka. The main lithic assemblage at San Quirce comes from Level III. The predominant tool types found in this level are hammerstones, manuports and flakes, with a small proportion of cores and a significant presence of denticulates. Adaptation to local environmental conditions resulted in distinctive cultural habits, which were embedded in the cultural tradition of hominins occupying the site during the final third of the Middle Pleistocene. San Quirce preserves a simple cultural tradition that was employed by local hominins to engage in a diverse array of activities, and highlights the cultural diversity that appears to have been a characteristic feature of the Lower to Middle Palaeolithic transition 300–200 ka.  相似文献